Studies on the Effects of Temperature and Particle Size on Bioremediation of AS (III) from Aqueous Solution Using Modified and Unmodified Coconut Fiber

نویسنده

  • J. C. Igwe
چکیده

Arsenic is an example of a heavy metal usually present in different types of industrial effluents. It is also responsible for environmental pollution and toxicity. Temperature and particle size are very crucial parameters in adsorption reactions. The effects of these two parameters on the bioremediation of As (III) from aqueous solution using modified and unmodified coconut fiber was investigated. The result showed that the most suitable temperature was 303K and 0.6mm is a better particle size than 0.3 mm. Various thermodynamic parameters, such as G , H , S and Ea were calculated. The values obtained for G , H and Ea were all 0 o o 0 o negative while those obtained for S were positive. The data showed that the sorption process is spontaneous o and exothermic in nature. The findings of this investigation suggest that physical sorption plays a significant role in controlling the sorption rate. The sticking probability model was further employed to assess the applicability of coconut fiber as an alternative adsorbent for As (III) contaminants in aqueous system. Therefore, these results could serve as design parameters in the treatment of arsenic from aqueous solution.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Sorption kinetics and intrapaticulate diffusivity of As(III) bioremediation from aqueous solution, using modified and unmodified coconut fiber

The pollution and toxicity problems posed by arsenic in the environment have long been established. Hence, the removal and recovery remedies have been sought, bearing in mind the efficiency, cost effectiveness and environmental friendliness of the methods employed. The sorption kinetics and intraparticulate diffusivity of As (III) bioremediation from aqueous solution using modified and unmodifi...

متن کامل

Adsorption of Basic Blue 41 from Aqueous Solution onto Coconut Fiber Particles

In this research, adsorption experiments were carried out for removal of Basic Blue 41(BB41) dye from an aqueous solution, using coconut fiber particles (CFP) as a low-cost biosorbent. The characteristics of coconut fiber particles weredeterminedwith a scanning electron microscope (FE-SEM) and Fourier Transform Infrared (FTIR) techniques. The effects of initial pH, biosorbentdose, contact time,...

متن کامل

Adsorption of Malachite Green from Aqueous Solution using Activated Ntezi Clay: Optimization, Isotherm and Kinetic Studies

The adsorption of malachite green from aqueous solution using a local low cost adsorbent, acid activated Ntezi clay, was investigated. The low cost adsorbent was activated with different concentrations of sulphuric acid and the physicochemical properties of the adsorbent were determined and the structural properties were analyzed using XRF and XRD. The adsorption process was studied as a functi...

متن کامل

Removal of Cerium from Aqueous Solutions by Amino Phosphate Modified Nano TiO2: Kinetic, and Equilibrium Studies

Adsorption of Ce(III) from aqueous solution by amino phosphate modified nano TiO2 was investigated. Effects of pH of solution, adsorbent dose, contact time, initial metal concentration and temperature were examined. Experimental data were fitted well by the pseudo second order model. Adsorption was well described by Freundlich isotherm model with a maximum adsorption capacity of 25 mg g-1. Acco...

متن کامل

From 4'-Hydroxy-2,2':6',2''-Terpyridine Complex of Chromium(III) towards Cr2O3 Nanoparticles: Effects of the Calcination Temperature on the Particle Size and Morphology

A new chromium(III) complex containing 4ʹ-hydroxy-2,2ʹ:6ʹ,2ʺ-terpyridine (tpyOH) has been prepared by the reaction of CrCl3. 6H2O with tpyOH in the presence of metallic zinc to afford the new complex [CrCl3(tpyOH)] (1). The complex 1 was used as a suitable precursor for the preparation of Cr2O3 nanoparticles by the simple calcination method at three different annealed temperatures of 400, 600, ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2013